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<b>污水處理</b> </h2> <div id="vb62q8t" class="display_title"> <h1>制藥廢水處理</h1> <div id="vb62q8t" class="info"> <span id="vb62q8t" class="font_size">文字：<a href="javascript:setFontSize(16);">[大]</a><a href="javascript:setFontSize(14);">[中]</a><a href="javascript:setFontSize(12);">[小]</a></span> <span id="vb62q8t" class="PublishedDate">2019-3-7 </span> <span id="vb62q8t" class="Hits">瀏覽次數：<b class="red" id="hits"></b> </span> <div id="vb62q8t" class="share_box"> <div id="vb62q8t" class="share_name">一鍵分享</div> <div style="display: none;background:#E9EBEA" class="share_content">  <div id="vb62q8t" class="bdsharebuttonbox"><a href="#" class="bds_more" data-cmd="more"></a><a href="#" class="bds_qzone" data-cmd="qzone" title="分享到QQ空間"></a><a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a><a href="#" class="bds_tqq" data-cmd="tqq" title="分享到騰訊微博"></a><a href="#" class="bds_renren" data-cmd="renren" title="分享到人人網(wǎng)"></a><a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a></div>  </div> </div> </div> <div id="vb62q8t" class="others enquiry"> </div>   </div> <div class="vb62q8t" id="info_content" class="display_content display_article"> <img src="http://tuoerjingroup.host1.china-21.com/uploads/200717/1-200GGG1043O.jpg" /><br /> <br /> <br /> <div> 　　1.一種制藥廢水的處理方法，其特征在于，包括如下步驟：第1步、將制藥廢水進(jìn)行生化處理;第2步、將生化處理的出水進(jìn)行氧化和/或超濾過(guò)濾處理;第3步、對第2步中的產(chǎn)水再用反滲透進(jìn)行處理。</div> <div> </div> <div> 　　2.根據權利要求1所述的制藥廢水的處理方法，其特征在于：所述的制藥廢水的COD在100～20000mg/L之間，色值在5～200之間;所述的制藥廢水含有至少一種以下的頑固COD成分：多環(huán)芳烴、雜芳化合物、氯化芳族化合物、硝基芳族化合物、芳族胺、芳族烯烴、芳族酯、聯(lián)苯或者有機氰化物。</div> <div> </div> <div> 　　3.根據權利要求1所述的制藥廢水的處理方法，其特征在于：所述的生化處理是指A2O方法;所述的生化處理步驟后，對產(chǎn)水進(jìn)行固液分離處理。</div> <div> </div> <div> 　　4.根據權利要求1所述的制藥廢水的處理方法，其特征在于：所述的氧化步驟是選自光化學(xué)氧化、催化濕式氧化、聲化學(xué)氧化、臭氧高級氧化、電化學(xué)氧化、Fenton氧化中的一種或者任意幾種的組合。</div> <div> </div> <div> 　　5.根據權利要求1所述的制藥廢水的處理方法，其特征在于：所述的超濾步驟中采用的超濾膜平均孔徑可以是5nm～50nm，或者為截留分子量是1000～200000Da的膜;所述的超濾的步驟中，溫度在5～70℃之間;壓力在0.05～1Mpa之間;膜面流速在0.5～10m/s之間。</div> <div> </div> <div> 　　6.根據權利要求1所述的制藥廢水的處理方法，其特征在于：所述的第2步中，是指先用氧化處理，再用超濾處理;所述的第2步中，在氧化處理后在產(chǎn)水中需要加入絮凝劑進(jìn)行絮凝處理。</div> <div> </div> <div> 　　7.一種制藥廢水的處理裝置，其特征在于，包括有生化處理單元(1)和反滲透膜(4)，所述的生化處理單元(1)通過(guò)氧化處理裝置(2)和/或超濾膜(3)與反滲透膜(4)相連接。</div> <div> </div> <div> 　　8.根據權利要求7所述的制藥廢水的處理裝置，其特征在于：所述的生化處理單元(1)依次通過(guò)氧化處理裝置(2)和超濾膜(3)與反滲透膜(4)相連接;在氧化處理裝置(2)與超濾膜(3)之間的管路上還可以連接有絮凝槽(5)，在絮凝槽(5)上還可以安裝有絮凝劑的加入裝置;生化處理單元(1)的結構中包括依次連接的厭氧反應池-缺氧反應池-好氧反應池。</div> <div> </div> <div> 　　9.根據權利要求7所述的制藥廢水的處理裝置，其特征在于：氧化處理裝置(2)可以采用光化學(xué)氧化反應器、催化濕式氧化反應器、聲化學(xué)氧化反應器、臭氧氧化反應器、電化學(xué)氧化反應器或者Fenton氧化反應器中的一種或者幾種的組合。</div> <div> </div> <div> 　　10.根據權利要求7所述的制藥廢水的處理裝置，其特征在于：超濾膜(3)的截留分子量范圍可以是在1000～200000Da或者其平均孔徑可以是5nm～50nm。</div> <div> </div> <div> 　　說(shuō)明書(shū)</div> <div> </div> <div> 　　一種制藥廢水的處理方法及裝置</div> <div> </div> <div> 　　技術(shù)領(lǐng)域</div> <div> </div> <div> 　　涉及一種制藥廢水的處理方法及裝置，屬于水處理技術(shù)領(lǐng)域。</div> <div> </div> <div> 　　背景技術(shù)</div> <div> </div> <div> 　　制藥廢水主要包括發(fā)酵類(lèi)生產(chǎn)廢水、化學(xué)合成藥物生產(chǎn)廢水、中藥生產(chǎn)廢水以及植物提取類(lèi)生產(chǎn)過(guò)程廢水四大類(lèi)。制藥工業(yè)廢水通常成分復雜，有機污染物種類(lèi)多、濃度高、COD值高且波動(dòng)性大，廢水的BOD5/COD值差異較大，色度深，毒性大，固體懸浮物SS濃度高等特點(diǎn)，是我國污染最嚴重、最難處理的工業(yè)廢水之一。</div> <div> </div> <div> 　　目前制藥廢水處理主體工藝采用“預處理+厭氧處理+好氧處理”，處理后的污水中還殘留一定量的難生物降解的雜環(huán)、多環(huán)芳烴化合物。因此需增加深度處理工藝來(lái)形成高溫、高壓的反應條件，同時(shí)提高自由基形成的數量，達到進(jìn)一步礦化有機物為二氧化碳和無(wú)機離子的目的，從而達到國家規定的排放要求。</div> <div> </div> <div> 　　國內外諸多學(xué)者對制藥廢水深度處理進(jìn)行了大量研究，各種物理、化學(xué)方法得到了廣泛應用，包括混凝沉淀法、吸附法、化學(xué)氧化法、電化學(xué)氧化法、光催化氧化法及膜分離等。目前的處理方法存在處理成本高、操作復雜、耐負荷沖擊能力差、不具有廣譜性等問(wèn)題。專(zhuān)利CN101863535A采用了電解法深度處理制藥廢水，電耗達到40.47KW·h/m3，高電耗導致實(shí)際運行成本過(guò)高。專(zhuān)利CN102807303A公布了一種制藥廢水深度處理工藝，該處理工藝適用廣譜性差，對其它類(lèi)制藥廢水處理效果不佳。</div> <div> </div> <div> 　　上述制藥廢水處理技術(shù)單獨用于廢水深度處理時(shí)或者現有的廢水處理技術(shù)組合，處理后的廢水均不能達到排放要求，并且其組合也難以適應化學(xué)成分復雜尤其是雜環(huán)化合物大的制藥廢水，因此有必要針對難處理的制藥廢水的處理工藝作進(jìn)一步的研究探索。</div> <div> </div> <div> 　　發(fā)明內容</div> <div> </div> <div> 　　本發(fā)明的目的是：提供一種可以解決高COD高色度的制藥廢水的處理方法及裝置。</div> <div> </div> <div> 　　技術(shù)方案是：</div> <div> </div> <div> 　　一種制藥廢水的處理方法，包括如下步驟：</div> <div> </div> <div> 　　第1步、將制藥廢水進(jìn)行生化處理;</div> <div> </div> <div> 　　第2步、將生化處理的出水進(jìn)行氧化和/或超濾過(guò)濾處理;</div> <div> </div> <div> 　　第3步、對第2步中的產(chǎn)水再用反滲透進(jìn)行處理。</div> <div> </div> <div> 　　所述的制藥廢水的COD在200～50000mg/L之間，色值在8～300之間。</div> <div> </div> <div> 　　所述的制藥廢水含有包括發(fā)酵類(lèi)生產(chǎn)廢水、化學(xué)合成藥物生產(chǎn)廢水、中藥生產(chǎn)廢水或者植物提取類(lèi)生產(chǎn)過(guò)程廢水中的一種或者幾種的混合物。</div> <div> </div> <div> 　　所述的生化處理是指A2O方法。</div> <div> </div> <div> 　　所述的生化處理步驟后，對產(chǎn)水進(jìn)行固液分離處理。</div> <div> </div> <div> 　　所述的氧化步驟是選自光化學(xué)氧化、催化濕式氧化、聲化學(xué)氧化、臭氧高級氧化、電化學(xué)氧化、Fenton氧化中的一種或者任意幾種的組合。</div> <div> </div> <div> 　　所述的超濾步驟中采用的超濾膜平均孔徑可以是5nm～50nm，或者為截留分子量是1000～200000Da的膜。</div> <div> </div> <div> 　　所述的超濾的步驟中，溫度在5～70℃之間;壓力在0.05～1Mpa之間;膜面流速在0.5～10m/s之間。</div> <div> </div> <div> 　　所述的第2步中，是指先用氧化處理，再用超濾處理。</div> <div> </div> <div> 　　所述的第2步中，在氧化處理后在產(chǎn)水中需要加入絮凝劑進(jìn)行絮凝處理。</div> <div> </div> <div> 　　所述的第3步中得到的反滲透濃縮液再返回第2步中進(jìn)行處理，最好是將反滲透濃縮液進(jìn)行電滲析除鹽后再依次送入氧化、絮凝、超濾步驟處理。</div> <div> </div> <div> 　　一種制藥廢水的處理裝置，包括有生化處理單元和反滲透膜，所述的生化處理單元通過(guò)氧化處理裝置和/或超濾膜與反滲透膜相連接。</div> <div> </div> <div> 　　所述的生化處理單元依次通過(guò)氧化處理裝置和超濾膜與反滲透膜相連接。</div> <div> </div> <div> 　　在氧化處理裝置與超濾膜之間的管路上還可以連接有絮凝槽，在絮凝槽上還可以安裝有絮凝劑的加入裝置。</div> <div> </div> <div> 　　生化處理單元的結構中包括依次連接的厭氧反應池-缺氧反應池-好氧反應池。</div> <div> </div> <div> 　　氧化處理裝置可以采用光化學(xué)氧化反應器、催化濕式氧化反應器、聲化學(xué)氧化反應器、臭氧氧化反應器、電化學(xué)氧化反應器或者Fenton氧化反應器中的一種或者幾種的組合。</div> <div> </div> <div> 　　超濾膜3的截留分子量范圍可以是在1000～200000Da或者其平均孔徑可以是5nm～50nm。</div> <div> </div> <div> 　　反滲透膜的濃縮側與氧化處理裝置的進(jìn)水口連接。最好是先經(jīng)過(guò)電滲析系統，再與氧化處理裝置的進(jìn)水口連接。</div> <div> </div> <div> 　　有益效果</div> <div> 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